Square well model
The Square well model is given by
- Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \Phi\left( r \right) = \left\{ \begin{array}{ccc} \infty & ; & r < \sigma \\ - \epsilon & ; &\sigma \le r < \lambda \sigma \\ 0 & ; & r \ge \lambda \sigma \end{array} \right. }
where is the intermolecular pair potential, r is the distance, σ is the hard diameter and λ > 1.
Equation of state
- Main article: Equations of state for the square well model
Virial coefficients
- Main article: Square well potential: virial coefficients
Critical point
References
- J. A. Barker and D. Henderson "Perturbation Theory and Equation of State for Fluids: The Square-Well Potential", Journal of Chemical Physics 47 pp. 2856-2861 (1967)
- Elisabeth Schöll-Paschinger, Ana Laura Benavides and Ramon Castañeda-Priego "Vapor-liquid equilibrium and critical behavior of the square-well fluid of variable range: A theoretical study", Journal of Chemical Physics 123 234513 (2005)
- R. López-Rendón, Y. Reyes and P. Orea "Thermodynamic properties of short-range square well fluid", Journal of Chemical Physics 125 084508 (2006)