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'''Patchy particles''' <ref>[http://dx.doi.org/10.1021/nl0493500 Zhenli Zhang and Sharon C. Glotzer "Self-Assembly of Patchy Particles", Nano Letters '''4''' pp. 1407-1413 (2004)]</ref>  | '''Patchy particles''' <ref>[http://dx.doi.org/10.1021/nl0493500 Zhenli Zhang and Sharon C. Glotzer "Self-Assembly of Patchy Particles", Nano Letters '''4''' pp. 1407-1413 (2004)]</ref> are models designed to keep pace with the rapid advances in the field of [[colloids]]. It is now possible to synthesise or fabricate tiny particles that have a variety of shapes, composition etc. In order to simulate these structures, there is a corresponding growth in the number of [[idealised models]] being developed and studied. With a view to classifying  | ||
==  | these "patchy" models the idea of "anisotropy dimensions" has been put forward.  | ||
Anisotropy dimensions is a classification scheme for patchy particles   | ==Taxonomy: anisotropy dimensions==  | ||
Anisotropy dimensions is a classification scheme for patchy particles <ref>[http://dx.doi.org/10.1038/nmat1949 Sharon C. Glotzer and  Michael J. Solomon "Anisotropy of building blocks and their assembly into complex structures",  Nature Materials '''6''' pp. 557-562 (2007)]</ref>.  | |||
The eight attributes are as follows:  | The eight attributes are as follows:  | ||
====Surface coverage (A)====  | ====Surface coverage (A)====  | ||
:[[Image:patchy_dimension_A.png|500px]]  | :[[Image:patchy_dimension_A.png|500px]]  | ||
====Aspect ratio (B)====  | ====Aspect ratio (B)====  | ||
:::[[Image:patchy_dimension_B.png|500px]]  | |||
====Faceting (C)====  | ====Faceting (C)====  | ||
:[[Image:patchy_dimension_C.png|500px]]  | |||
====Pattern quantisation (D)====  | ====Pattern quantisation (D)====  | ||
:[[Image:patchy_dimension_D.png|500px]]  | |||
====Branching (E)====  | ====Branching (E)====  | ||
:[[Image:patchy_dimension_E.png|500px]]  | |||
====Chemical ordering (F)====  | ====Chemical ordering (F)====  | ||
:::[[Image:patchy_dimension_F.png|500px]]  | |||
====Shape gradient (G)====  | ====Shape gradient (G)====  | ||
:::[[Image:patchy_dimension_G.png|500px]]  | |||
====Roughness (H)====  | ====Roughness (H)====  | ||
::[[Image:patchy_dimension_H.png|500px]]  | |||
==Models==  | ==Models==  | ||
*[[Bol model of water]]  | *[[Bol model of water]]  | ||
*[[Dahl and Andersen model of water]]  | *[[Dahl and Andersen model of water]]  | ||
*[[Inverse patchy colloids]]  | |||
*[[Kern and Frenkel patchy model]]    | *[[Kern and Frenkel patchy model]]    | ||
*[[Modulated patchy Lennard-Jones model]]  | *[[Modulated patchy Lennard-Jones model]]  | ||
*[[Smith and Nezbeda associated fluid model]]  | *[[Smith and Nezbeda associated fluid model]]  | ||
*[[Laponite]]  | |||
==See also==  | ==See also==  | ||
*[[Colloids]]  | *[[Colloids]]  | ||
| Line 23: | Line 35: | ||
*[[Janus particles]]  | *[[Janus particles]]  | ||
*[[Phase diagram of anisotropic particles with octahedral symmetry]]  | *[[Phase diagram of anisotropic particles with octahedral symmetry]]  | ||
*[[  | *[[Anisotropic particles with tetrahedral symmetry]]  | ||
*[[Wertheim's first order thermodynamic perturbation theory (TPT1)]]  | *[[Wertheim's first order thermodynamic perturbation theory (TPT1)]]  | ||
*[[TPT-CF| Multi-patch RTPT-CF]]  | |||
==References==  | ==References==  | ||
| Line 30: | Line 43: | ||
'''Related reading'''  | '''Related reading'''  | ||
*[http://dx.doi.org/10.1002/marc.200900614 Amar B. Pawar and Ilona Kretzschmar "Fabrication, Assembly, and Application of Patchy Particles", Macromolecular Rapid Communications '''31''' pp. 150-168 (2010)]  | *[http://dx.doi.org/10.1002/marc.200900614 Amar B. Pawar and Ilona Kretzschmar "Fabrication, Assembly, and Application of Patchy Particles", Macromolecular Rapid Communications '''31''' pp. 150-168 (2010)]  | ||
*[http://dx.doi.org/10.1038/nmat2927 Willem K. Kegel and Henk N. W. Lekkerkerker "Colloidal gels: Clay goes patchy", Nature Materials '''10''' pp. 5-6 (2011)]  | |||
*[http://dx.doi.org/10.1021/la3017563 Zhenping He and Ilona Kretzschmar "Template-Assisted Fabrication of Patchy Particles with Uniform Patches", Langmuir '''28''' pp. 9915-9919 (2011)]  | |||
[[category: models]]  | [[category: models]]  | ||
Latest revision as of 12:27, 23 March 2015
Patchy particles [1] are models designed to keep pace with the rapid advances in the field of colloids. It is now possible to synthesise or fabricate tiny particles that have a variety of shapes, composition etc. In order to simulate these structures, there is a corresponding growth in the number of idealised models being developed and studied. With a view to classifying these "patchy" models the idea of "anisotropy dimensions" has been put forward.
Taxonomy: anisotropy dimensions[edit]
Anisotropy dimensions is a classification scheme for patchy particles [2]. The eight attributes are as follows:
Surface coverage (A)[edit]
Aspect ratio (B)[edit]
Faceting (C)[edit]
Pattern quantisation (D)[edit]
Branching (E)[edit]
Chemical ordering (F)[edit]
Shape gradient (G)[edit]
Roughness (H)[edit]
Models[edit]
- Bol model of water
 - Dahl and Andersen model of water
 - Inverse patchy colloids
 - Kern and Frenkel patchy model
 - Modulated patchy Lennard-Jones model
 - Smith and Nezbeda associated fluid model
 - Laponite
 
See also[edit]
- Colloids
 - Emulsions
 - Janus particles
 - Phase diagram of anisotropic particles with octahedral symmetry
 - Anisotropic particles with tetrahedral symmetry
 - Wertheim's first order thermodynamic perturbation theory (TPT1)
 - Multi-patch RTPT-CF
 
References[edit]
Related reading
- Amar B. Pawar and Ilona Kretzschmar "Fabrication, Assembly, and Application of Patchy Particles", Macromolecular Rapid Communications 31 pp. 150-168 (2010)
 - Willem K. Kegel and Henk N. W. Lekkerkerker "Colloidal gels: Clay goes patchy", Nature Materials 10 pp. 5-6 (2011)
 - Zhenping He and Ilona Kretzschmar "Template-Assisted Fabrication of Patchy Particles with Uniform Patches", Langmuir 28 pp. 9915-9919 (2011)